1. Create a new document, use Rectangular Marquee Tool to make a rectangle with round edge and fill it with black color
2. Go to Blending Options
3. Create a new layer, use Rectangular Marquee Tool to make a smaller rectangular shape inside, with 2px gap between the inside and outside rectangles, fill the color and go to Blending Options
After that, you will get the result:
4. This step you will make up the button, use Linear Gradient with black color, selection 1px, you will get the result like this:
Customize your colors for gradient to look good
This is my final result:
More Tutorials: 
